Publications
Publications
Here are the publications that have resulted from my time as a research chemist.
The graphics act as links to the articles on the various publisher sites.
Happy reading!
Strategies for the Photoreduction of Tc‐99 Pertechnetate to Low‐Valent Tc by Keggin Polyoxometalate
Radivojevic Jovanovic, I., Gallagher, C.M.B., Salcedo, R., Lukens, W.W., Jr., Burton‐Pye, B.P., McGregor, D. and Francesconi, L.C.; European Journal of Inorganic Chemistry, 2020: 2133-2142. doi:10.1002/ejic.202000170
Synthesis and Characterization of Non-Aqueous [(TcM)-M-X-PW11O39]n- with M=O, N: Comparing TcV and TcVI in Metal Oxide Matrices
Burton-Pye, B.P.; Dembowski, M.; Lukens, W. W., Jr.; Cruz, A.; Althour, A.; Lopez, G.E.; Salcedo, R.; Gallagher, C.M.B.; McGregor, D.; Francesconi, L.C.; European Journal of Inorganic Chemistry. 2019, 4826-4834. DOI: 10.1002/ejic.201900864
Speciation and reactivity of heptavalent technetium in strong acids.
Poineau, F.; Burton-Pye, B.P.; Sattelberger, A.P.; Czerwinski, K.R.; German, K.E.; Fattahi, M.; New Journal of Chemistry, 2018, 42(10), 7522-7528. DOI: 10.1039/C7N04912A
Photochemical behavior of the quadruply metal-metal bonded [Tc2Cl8]2-anion in acetonitrile.
Burton-Pye, Benjamin P.; Poineau, Frederic; Bertoia, Julie; Czerwinski, Kenneth R.; Francesconi, Lynn C.; Sattelberger, Alfred P.; Inorganica Chimica Acta. 2016, 453, 724-727. DOI: 10.1016/j.ica.2016.09.041
Aggregation of Heteropolyanions in Aqueous Solutions Exhibiting Short-Range Attractions and Long-Range Repulsions.
Bera, Mrinal K.; Qiao, Baofu; Seifert, Soenke; Burton-Pye, Benjamin P.; Oliviera de la Cruz, Monica; Antonio, Mark R.; Journal of Physical Chemistry C. 2016, 120, 1317-1327. DOI: 10.1021/acs.jpcc.5b10609
p-SCN-BN-HOPO: A Superior Bifunctional Chelator for Zr ImmunoPET.
Deri, Melissa; Ponalla, Sashikanth; Kozlowski, Paul; Burton-Pye, Benjamin P.; Cicek, Husseyin; Hu, Chinua; Lewis, Jason S.; Francesconi, Lynn C.; Bioconjugate Chemistry. 2015, 26, 2579-2591. DOI:10.1021/acs.bioconjchem.5b00572
Speciation of Technetium Peroxo Complexes in Sulfuric Acid Revisited.
Poineau, Frederic; German, Konstantin E.; Burton-Pye Benjamin P.; Weck Philippe F.; Kim, Eunja; Kriyzhovets, Olga; Safonov, Aleksey; Ilin, Viktor; Francesconi, Lynn C.; Sattelberger, Alfred P.; Czerwinski, Kenneth R.; Journal of Radioanalytical and Nuclear Chemistry (APSORC2013 Proceedings). 2015, 303(2), 1163-1167. DOI: 10.1007/s10967-014-3434-1
Structural aspects of heteropolyacid microemulsions.
Bera, Minral K.; Ellis, Ross J.; Burton-Pye, Benjamin P.; Antonio, Mark R.; Physical Chemistry Chemical Physics. 2014, 16,22566-22574. DOI: 10.1039/c4cp03014a
Insights into stabilization of the 99TcVO core for synthesis of 99TcVO compounds.
McGregor, Donna; Burton-Pye, Benjamin P.; Lukens, Wayne W.; Francesconi, Lynn C.; European Journal of inorganic Chemistry. 2014, 6, 1082-1089. DOI: 10.1002/ejic.201301034
Diperoxo Pertechnetic Acid Characterized by Spectroscopic and Quantum Chemical Studies.
Poineau, Frederic; Weck, Philippe F.; Burton-Pye, Benjamin P.; Kim, Eunja; Francesconi, Lynn C.; Sattelberger, Alfred P.; German, Konstantin E.; Czerwinski, Kenneth R.; European Journal of inorganic Chemistry. 2013, 26, 4595-4600. DOI: 10.1002/ejic.201300383
On the Nature of Heptavalent Technetium in Concentrated Nitric and Perchloric Acid.
Poineau, Frederic; Burton-Pye, Benjamin P.; Maruk, Alesya; Kirakosyan, Gayane: Denden, Ibthihel; Rego, Daniel B.; Johnston, Erik V.; Sattelberger, Alfred P.; Fattahi, Massoud; Francesconi, Lynn C.; German, Konstantin E.; Czerwinski, Kenneth R.; Inorganica Chimica Acta; 2013, 398, 147-150. DOI:10.1016/j.ica.2012.12.028
Reactivity of Pertechnetic Acid in Sulfuric Acid: Technetium Sulfates Complexes Revealed by X-ray Absorption Spectroscopy and First Principles Calculations
Poineau, Frederic; Weck, Philippe F.; Burton-Pye, Benjamin P.; Denden, Ibthihel ; Kim, Eunja; Kerlin, William; Maruk, Alesya; Kirakosyan, Gayane; German, Konstantin E.; Fattahi, Massoud; Francesconi, Lynn C.; Sattelberger Alfred P.; Czerwinski, Kenneth R.; Dalton Transactions; 2013, 42, 4348-4352. DOI:10.1039/c3dt32951h
Ternary phthalocyanato Hf(IV) and Zr(IV) polyoxometalate complexes.
Radivojevic, Ivana; Ithisuphalap, Kemakorn; Burton-Pye, Benjamin P.; Saleh, Raihan; Francesconi, Lynn C.; Drain, Charles M.; Royal Society of Chemistry Advances; 2013, 3, 2174-2177. DOI:10.1039/c2ra22903j
99Tc and Re Incorporated into Metal Oxide Polyoxometalates: Oxidation State Stability Elucidated by Electrochemistry and Theory
Donna McGregor, Benjamin P. Burton-Pye, Israel M. Mbomekalle, Pablo A. Aparicio, Susanna Romo, Xavier Lopez, Josep Poblet and Lynn C. Francesconi.; Inorg. Chem., 2012, 16, 9017-9028. DOI:10.1021/ic3011713
Zirconium(IV) and Hafnium(IV) Porphyrin and Phthalocyanine Complexes as New Dyes for Solar Cell Devices
Ivana Radivojevic, Giorgio Bazzan, Benjamin P. Burton-Pye, Kemakorn Ithisupalup, Raihan Saleh, Michael F. Durstock, Lynn C. Francesconi and Charles Michael Drain; J. Phys. Chem. C, 2012, 116, 15867-15877. DOI: 10.1021/jp301853d
Investigation into the extraction speciation of rare-earth radioisotopes from aqueous solution using polyoxometalates.
Burton-Pye, Benjamin P.; Jones, India; Cutler, Cathy S.; Howell, Robertha C.; Francesconi, Lynn C. Inorganica Chimica Acta, 2012, 380, 236-243. DOI: 10.1016/j.ica.2011.09.022
Self-assembly between dicarboxylate ions and a binuclear europium complex: formation of stable adducts and heterometallic lanthanide complexes
James A. Tilney, Thomas Just Sørensen, Benjamin P. Burton-Pye and Stephen Faulkner; Dalton Trans., 2011, 40(45), 12063-12066. DOI: 10.1039/c1dt11103e
A binuclear lanthanide complex consisting of two lanthanide binding domains linked by a m-xylyl bridging unit forms very stable 1:1 adducts with benzene dicarboxylic acids and their derivatives. The complex with isophthalate derivatives is particularly stable.
Photoreduction of 99Tc Pertechnetate by Nanometer-Sized Metal Oxides: New Strategies for Formation and Sequestration of Low-Valent Technetium
Burton-Pye, Benjamin P.; Radivojevic, Ivana; McGregor, Donna; Mbomekalle, Israel M.; Lukens, Wayne W.; Francesconi, Lynn C.; Journal of the American Chemical Society; 2011, 133(46), 18802-18815. DOI: 10.1021/ja2060929
Speciation of organic-soluble europium(III) α1-Wells–Dawson complexes
Benjamin P. Burton-Pye* and Lynn C. Francesconi; Dalton Trans., 2011, 40, (17), 4421-4433. DOI: 10.1039/C0DT1309A
Synthesis, Structure Elucidation, and Redox Properties of 99Tc Complexes of Lacunary Wells−Dawson Polyoxometalates: Insights into Molecular 99Tc−Metal Oxide Interactions
Donna McGregor, Benjamin P. Burton-Pye, Robertha C. Howell, Israel M. Mbomekalle, Wayne W. Lukens, Jr., Fang Bian, Edward Mausolf, Frederic Poineau, Kenneth R. Czerwinski and Lynn C. Francesconi; Inorg. Chem., 2011, 50, (5), 1670. DOI: 10.1021/ic102111t
Series behavior of lanthanoid(III) complexes with the α-1-Wells-Dawson heteropolyoxoanion in acetonitrile: electrochemistry and Ln coordination
Mark R. Antonio, Jing Jing, Benjamin P. Burton-Pye and Lynn C. Francesconi; Dalton Trans., 2010, 7980. DOI: 10.1039/c0dt00394h
Ternary Porphyrinato HfIV and ZrIV Polyoxometalate Complexes
Alexander Falber, Benjamin P. Burton-Pye, Ivana Radivojevic, Louis Todaro, Raihan Saleh, Lynn C. Francesconi and Charles M. Drain; Eur, J. Inorg. Chem., 2009, 17, 2459. DOI: 10.1002/ejic.200900284
Europium(III) Reduction and Speciation within a Wells−Dawson Heteropolytungstate
Jing Jing, Benjamin P. Burton-Pye, Lynn C. Francesconi and Mark Antonio; Inorg. Chem., 2008, 47, (15), 6889. DOI: 10.1021/ic800465e
Influence of the lanthanide ion and solution conditions on formation of lanthanide Wells-Dawson polyoxotungstates
Cheng Zhang, Laurence Bensaid, Donna McGregor, Xikui Fang, Robertha C. Howell, Benjamin P. Burton-Pye, Qunhui Luo, Louis Todaro and Lynn C. Francesconi; Journal of Cluster Sci., 2006, 17, (2), 389. DOI: 10.1007/s10876-006-0066-9
Self-assembly of luminescent ternary complexes between seven-coordinate lanthanide(III) complexes and chromophore bearing carboxylates and phosphonates
Simon J. A. Pope, Benjamin P. Burton-Pye, Rory Berridge, Tahir Kahn, Peter J. Skabara and Stephen Faulkner; Dalton Trans., 2006, 2907. DOI: 10.1039/b600598e
Production and Reactions of Organic-Soluble Lanthanide Complexes of the Monolacunary Dawson [α1-P2W17O61]10- Polyoxotungstate
Cécile Boglio, Géraldine Lenoble, Carine Duhayon, Bernold Hasenknopf, René Thouvenot, Cheng Zhang, Robertha C. Howell, Benjamin P. Burton-Pye, Lynn C. Francesconi, Emmanuel Lacôte, Serge Thorimbert, Max Malacria, Carlos Afonso, and Jean-Claude Tabet; Inorg. Chem., 2006, 45 (3), 1389. DOI:10.1021/ic051679g
Simon J. A. Pope, Benjamin P. Burton-Pye and Stephen Faulkner; Appl. Spec. Rev., 2005, 40, 1. DOI :10.1081/ASR-200038308
In this article, imaging applications of luminescent complexes and recent advances in the design and photophysical behaviour of near-IR responsive complexes are reviewed. Various properties of the luminescent lanthanide complexes are also discussed in detail. (86 references).
Synthesis and luminescence properties of lanthanide complexes incorporating a hydralazine-derived chromophore
Benjamin P. Burton-Pye, Sarah L. Heath and Stephen Faulkner; Dalton Trans., 2005, 146. DOI: 10.1039/b413005g
Reaction of 1-hydrazinophthalazine with chloroacetyl chloride yields 3-chloromethyl-1,2,4-triazolo-phthalazine. Reaction of this product with the tris tert-butyl ester of DO3A yields a triazolophthalazine appended macrocycle. Hydrolysis and complexation with lanthanide ions gives access to a series of lanthanide complexes (Ln = Nd, Eu, Yb, Er); these are all luminescent and exhibit sensitisation of the lanthanide centre by the chromophore.
pH Dependent self-assembly of dimetallic lanthanide complexes
Stephen Faulkner and Benjamin P. Burton-Pye; Chem Commun., 2005, 259. DOI: 10.1039/b412329h
pH dependent self-association has been observed in a series of DO3A-derived lanthanide complexes bearing a carboxylate group that can act as a bridging ligand at high pH, switching on the luminescence from the lanthanide.
Imaging with luminescent lanthanide complexes
R. J. Aarons, B. P. Burton-Pye, S. Faulkner, S. W. Botchway, A. W. Parker, S. Topley, A. Beeby, J. S. Snaith, A. Ashraf, J. Notta.; Lasers for Science Annual Report, 2002, 130
Interaction between tetrathiafulvalene carboxylic acid and ytterbium DO3A: solution state self-assembly of a ternary complex which is luminescent in the near IR
Stephen Faulkner, Benjamin P. Burton-Pye, Tahir Kahn, Leigh R Martin, Steven D. Wray and Peter J. Skabara; Chem. Commun., 2002, 1668. DOI: 10.1039/b204218e
Synthesis and near-IR luminescence properties of neodymium(III) and ytterbium(III) complexes with poly(pyrazolyl)borate ligands
Andrew Beeby, Benjamin P. Burton-Pye, Stephen Faulkner, Graham R. Motson, John C. Jeffery, Jon A. McCleverty and Michael D. Ward; Dalton Trans., 2002, 1923. DOI: 10.1039/b200519k
